I have used all kinds. It is neither the best or worst idea; just trade-offs. Stainless steel has virtually no stretch compared to synthetics, so you get instant response and control. You get some delay with synthetics (but I think the Q-power that Think uses has less stretch than dyneema line – but still some, compared to steel).
It is relatively easy to restring synthetics, usually no tools required, just a passable skill at knotting.
Stainless steel, despite the name, does suffer some corrosion over time, and, since it is braided strands, corrosion can happen within the braid, making it harder to detect – when they let go, they just go. Synthetics are more prone to abrasion on the outside, perhaps easier to detect (assuming the line is inspected from time to time). Still, best to replace any type of line on a periodic basis.
In the case of flat-water or small wave paddling, I don’t think the steering delay is an issue, so my personal preference is to opt for a synthetic just because they are easier to maintain.
Where I believe there is a noticeable difference is when you are paddling big water that requires turning to carve across the face of waves in order to link your runs – the responsiveness of the wire is nice to have in that situation. Of course, the better the paddler one becomes, the less the type of equipment matters compared to the paddler (i.e., for the top paddlers, it is probably makes little difference).
While you could conceivably re-tie a synthetic if it breaks while you are out paddling, it would still be a pain, especially in heavy seas, so you need to ensure you have some type of backup device to allow steering if you break either type of line.
Not sure if I have helped. The one thing I do know is that while I love the responsiveness of steel, I so wish it was synthetic when it comes time to change it.
Bill L